| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2471 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Catalytic decomposition of ammonia by Ru/La(x)-Al2O3 (x=0, 1, 5, 10, and 50 mol%) |
| 초록 | Owing to the facile transportability and high hydrogen storage density (17.7 wt% and 108 g/L @ 0.86 MPa and 20 ℃), ammonia has been considered as an attractive hydrogen energy carrier. In addition, ammonia decomposition releases no COx, and the spent-fuel N2 can be regenerated via the well-established Haber-Bosch process. Due to the high kinetic barrier, however, the NH3 dehydrogenation needs high temperature. It is therefore necessary to develop highly active and thermally stable catalysts for practical applications. We investigated Ru-based catalysts supported on La-doped alumina, and found that the as-developed catalyst showed superior activities at 550 ℃ with the conversion of ＞ 99.5%. The Influence of La doping was further assessed as a function of La concentration. Key words : Ammonia dehydrogenation, Hydrogen storage, Catalyst, Ru, La doped alumina, LaAlO3 |
| 저자 | 김효영1, 김영천2, 장성철2, 박현서2, 한종희2, 남석우2, 윤창원2 |
| 소속 | 1고려대, 2한국과학기술(연) |
| 키워드 | 비균질촉매; 크래킹촉매; 리포밍촉매 |
| 원문파일 | 초록 보기 |
