| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Chain Stretching of Asymmetric polystyrene-block-poly(2-vinyl pyridine) copolymers by Coordination with Metal Chloride |
| 초록 |
The morphology and phase transition of asymmetric polystyrene-block-poly(2-vinyl pyridine) copolymer [S2VP] coordinated with cadmium chloride [CdCl2] were studied by rheology, SAXS, and TEM. The order-disorder [ODT] and order-order transition [OOT] were increased greatly with CdCl2. Also, the microdomain of neat S2VP was transformed into another microdomain with the addition of CdCl2. This is due to the fact that S2VP chains become more stiffened and stretched vertically to the interface between PS and P2VP. Acknowledgement: This work was supported by Creative Research Initiative Program supported by KOSEF |
| 저자 |
이동현1, 한성현1, 주원철1, 류두열2, 허준3, 김진곤1
|
| 소속 |
1포항공과대, 2연세대, 3서울대 |
| 키워드 |
polystyrene-block-poly(2-vinyl pyridine) copolymer; Metal Chloride; Phase Behavior
|
| E-Mail |
|
