화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-정밀화학
제목 Highly Sensitive SERS Probes with silica template structure based on Nanogap Control of Au-Ag Alloys
초록 Inthis study, we report how to fabricate a robust, reproducible and reliablesurface-enhanced Raman scattering (SERS) probe for high-sensitivity chemicaldetection. As a high-sensitivity SERS probe, SiO2@Au@Agnanoparticles (NPs) were synthesized by introducing Au NP seeds into a silicatemplate and growing Ag as an alloy type on its surface. The SERS activity ofSiO2@Au@Ag NPs is regulated by the AgNO3 concentration,and as the AgNO3 concentration increases, an Ag shell grows on theAu seed surface and a nanogap is formed between the two Ag nanoparticles on theprobe surface. The SERS signal intensity of SiO2@Au@Ag NPs wasdetermined using the Raman chemical 4-aminothiophenol (ATP). Since SiO2@Au@AgNPs have strong SERS signals, they can be applied as high-sensitivity SERSprobes and can be used for quantitative detection of trace chemicals. Inaddition, the excellent Raman signal reproducibility of SiO2@Au@AgNPs to 4-ATP has potential for use in in situ detection.



저자 함경민, 김재희, 김윤희, 김우연, 전봉현
소속 건국대
키워드 Au-Ag alloy; Silica nanoparticle; Surface-enhanced Raman scattering (SERS); SERS probe; nanogap
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