| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Solvent-Free Preparation of Fluorinated Polythiophene Nano-Particles by Supercritical CO2 RESOLV Process |
| 초록 |
We report a simple method to prepare surfactant-free and solvent-free nano-structured semi-conducing polymers by using supercritical carbon dioxide Recently, we have synthesized highly CO2-soluble fluoroalkyl ester substituted semi-conducting polymers using scCO2 as a solvent. Due to the fluorophilicity of CO2, the conjugated polymer, PSFTE was found to be highly soluble in scCO2 and produced nano size (50-100 nm) spherical particles upon expansion of supercritical solution (RESOLV) in to water or methanol through a small capillary nozzle. |
| 저자 |
김준호, Hullathy Subban Ganapathy, Seung Ho Kim, 임권택
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| 소속 |
부경대 |
| 키워드 |
Fluorinated Polythiophene; Supercritical CO2
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| E-Mail |
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