학회 | 한국공업화학회 |
학술대회 | 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
권호 | 20권 1호 |
발표분야 | 촉매_포스터 |
제목 | Effect of CO2 in the Toluene Side-chain Alkylation with Methanol |
초록 | By Far economic manufacture of styrene remains a challenge because the current industrial process suffers from drawbacks such as multi steps, high energy consumption and environmental impact. As an alternative method for the production of styrene from cheap raw materials like toluene and methanol was proposed by several groups including our group. Zeolites are widely used in the side chain alkylation of toluene using methanol because of their unique properties like uniform pore size, high thermal stability and tunable basicity by ion exchange or impregnation with (K, Na, Cs and Ba) as the reaction proceeds via base catalysis. In this work, we studied the effect of temperature with ion-exchanged zeolite X under CO2 flow in the side-chain alkylation of toluene with methanol. The effect of CO2 on the activity and selectivity in the side-chain alkylation of toluene with methanol will be discussed. |
저자 | 서동우1, 박상언1, Nanzhe Jiang2 |
소속 | 1인하대, 2연변대 |
키워드 | Side-chain alkylation; CO2; Styrene |