| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
분자전자 소재 및 소자 기술(분자전자 부문위원회) |
| 제목 |
Synthesis and Properties of Soluble and Stable Silyl End-Capped Bis-Thienylanthracene Oligomers for Organic Thin Film Transistors |
| 초록 |
A series of new organic semiconductors dimethyl-n-octylsilyl end-capped thiophene-anthracene oligomers containing 9,10-anthracene moiety in the center have been synthesized using palladium-catalyzed Stille coupling reactions. The synthesized bis-silylated thiophene-anthracene oligomers were characterized by 1H-NMR, 13C-NMR and high-resolution mass spectroscopy, and are observed to have remarkably high solubility in common organic solvents. Their optical, thermal and electrochemical properties were measured. Absorption maxima of bis-quarterthienylanthracene in solution is closer to those obtained α,ω-dihexylsexithiophene (DH-6T). Electrochemical measurements indicate that bis-silylated thiophene-anthracene oligomers have better oxidation stability than the corresponding oligothiophenes without anthracene core. Bis-quarterthienylanthracene still has low HOMO level in spite that it contains totally nine arene rings in the oligomeric molecules. |
| 저자 |
최정희, 박혜정, 진성호, 윤웅찬
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| 소속 |
부산대 |
| 키워드 |
Thiophene oligomer; bis-oligothienylanthracene; Silyl end-capping group; Stille reaction
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| E-Mail |
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