화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 에너지저장변환_포스터
제목 Phosphorus-doped porous carbon derived from biomass for sodium ion capacitors
초록 Sodium ion capacitor is considered as very attractive an alternative to lithium-ion energy storage due to the abundance and low cost of sodium. However, during the charging and discharging processes, the metal-based electrode for Na-ion energy storage system often shows poor intrinsic electrical conductivity and large capacity decay. Here, we report a high-performance Na-ion energy storage device using novel phosphorous-doped porous carbon derived from renewable, sustainable and accessible biomass, empty fruit bunch (EFB) by a thermal process. The carbon nanomaterials have highly active sites and well-developed pores with the highest surface area of ~ 1154.2 m2 g-1 and high mass content of phosphorus of ~ 19.67 %. The biomass derived electrode for Na-ion capacitor exhibits a high capacity of ~233.81 F g-1, long cycle life of ~ 96 % after 1000 cycles and stable rate capability of ~ 70 % at scan rate 70 mV s-1.  
저자 박호석, 박슬기
소속 성균관대
키워드 sodium ion capacitor; biomass; phosphorus; doping; steam activation; empty fruit bunch
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