| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
| 권호 |
14권 2호, p.2814 |
| 발표분야 |
에너지 |
| 제목 |
Novel Thermal Swing Sorption Enhanced Reaction Process for Simultaneous Production of H2 and CO2 from Synthesis Gas Produced by Coal Gasification |
| 초록 |
The goal of this study is to test the feasibility of a novel concept called thermal swing sorption enhanced reaction (TSSER) process to carry out simultaneously the water gas shift (WGS) reaction for the production of a pure stream of H2 (dry basis) and the separation of CO2 as a single unit operation in a sorber-reactor. The sorption enhanced reaction (SER) can circumvent the thermodynamic limitation of the WGS reaction and enhance the rate of the forward reaction. New equilibrium and column dynamic data for chemisorption of CO2 from inert N2 on K2CO3 promoted hydrotalcite and Na2O promoted alumina were measured. The SER concept was successfully tested using a commercial WGS catalyst and the chemisorbents by both experiments and numerical simulations. The proposed TSSER process was numerically simulated and the results show that the TSSER process is capable of directly producing a fuel-cell grade H2 product (~10 ppm CO) at feed gas pressure using synthesis gas as the reactor feed. The TSSER process also produces a pure and compressed CO2 by-product. |
| 저자 |
이기봉1, Michael G. Beaver2, Hugo S. Caram2, Shivaji Sircar2
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| 소속 |
1한국에너지기술(연), 2Lehigh Univ. |
| 키워드 |
Thermal swing process; Sorption enhanced reaction; Chemisorption; Hydrogen; Carbon dioxide
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| E-Mail |
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| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
