| 초록 |
Amine-terminated butadiene-acrylonitrile (ATBN) was covalently grafted on a hexagonal boron nitride (BN) surface to enhance the interface affinity between BN and a carboxylated styrene-butadiene rubber (XSBR) matrix for preparing thermal interface materials with robust thermo-physical properties. The mechanical properties, thermal stability, thermal conductivity, thermo-physical properties, and interfacial filler–matrix network of the prepared XSBR/ABN nanocomposites were studied. The XSBR/ABN nanocomposites exhibited better mechanical and thermo-physical behavior compared to the XSBR/BN nanocomposites over the entire range of filler concentration. Moreover, the XSBR/ABN nanocomposites exhibited superior thermal conductivity as compared to the XSBR/BN nanocomposites, with the former exhibiting approximately 490% higher thermal conductivity than neat XSBR, whereas the latter exhibited 395% higher thermal conductivity than neat XSBR at a filler loading of 90 phr. |
