화학공학소재연구정보센터
학회 한국재료학회
학술대회 2008년 봄 (05/22 ~ 05/23, 상록리조트)
권호 14권 1호
발표분야 전자재료
제목 Effects of different Mn ion valences in CMR materials to electrical and structural properties
초록 Colossal magnetoresistance (CMR) of perovskite Mn oxides (L1-xAxMnO3 where L and A are trivalent rare-earth ions and divalent alkaline earth ions, respectively) are received technological importance because their high TCR values. Due to this high TCR property, LSMO(La1-xSrxMnO3) can be served as a resistor material for uncooled microbolometer. The metallic conductivity and ferromagnetism of CMR thin films can be explained in terms of Zener-type double exchange between the spin-aligned Mn3+ and Mn4+ ions through oxygen ions. In this research, the effects of different Mn ion valences to structural and electrical properties of CMR materials were investigated with LSMO and LBMO(B=Ba) films with same tolerance factor, i.e., no stain difference in the film. And we revealed a correlation between strain and Mn valences of thin films which affect TCR value and structural and micro grain states of thin films
저자 Sun Gyu Choi1, Hyung-Ho Park2, A. Sivasankar Reddy1, Byoung-Gon Yu2, Hojun Ryu1
소속 1Department of Ceramic engineering, 2Yonsei Univ.
키워드 CMR; microbolometer; tolerance factor; Mn valence
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