화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-환경·에너지
제목 Adsorption properties of mono-dispersed DDR zeolite particles for CO​2, N2, and H2O
초록 Si-DDR zeolites have proper pore size to separateCO2 from N2 based on the size difference. Even though Si-DDR zeolites have potentialas CO2 separator, synthetic method using mono-dispersed DDR zeolites have not beenwidely used. We present the synthesis method of mono-dispersed Si-DDR which havediamond shape by using seeded growth of irregular Si-DDR particles. In Si-DDR particles,the adsorption isotherms and heat of adsorption of CO2, N2, and H2O were goodenough to compare with the literature. At 303 K, CO2/N2 ideal sorption weremeasured ~15.3-18.0 and permeation selectivities were measured ~7.7-9.0. Theseresult means that all silica DDR zeolites are active as a membrane for CO2/N2separations. Furthermore, the presence of H2O affects the quantity of defectsin Si-DDR framework.



저자 심재희, 김은주, 최정규
소속 고려대
키워드 Seeded growth; DDR zeolites; Adsorption
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