| 학회 | 한국화학공학회 |
| 학술대회 | 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 | 15권 1호, p.1118 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Catalytic oxidation over Ti containing 3-D mesoporous silica |
| 초록 | Ti-incorporated mesoporous silica has been used as an excellent catalyst for various industrial fundamental applications such as oxidation reactions. The Ti-TUD-1 type hierarchical mesoporous silica materials having three-dimensional pore structure were prepared by non templating method. The TUD-1 could be synthesized by using an oligomarizable monomer such as TEA (Triethanolamine) with microwave. The TEA is used as excellent chelating agent provoked a surfactant-free pathway and assisted well homogeneously dispersion of metal complex onto mesoporous surface. The Ti-contaning TUD-1 mesoporous silica has high catalytic activity and selectivity in the oxidation of olefins due to especially excellence in metal or metal oxides incorporation and impregnation, and high surface area. Reference [1] Z. Shan, E. Gianotti, J.C. Jansen, J. Peters, L. Marchese, T. Maschmeyer, Chemistry-A European Journal(2001),7(7),1437-1443 [2] Z.Shan, J.C. Jansen, L. Marchese, Th.Maschmeyer, Microporous and Mesoporous Materials 48 (2001) 181-187 |
| 저자 | 정승민, 박상언 |
| 소속 | 인하대 |
| 키워드 | Catalytic oxidation; Ti containing 3-D mesoporous silica |
| 원문파일 | 초록 보기 |
