화학공학소재연구정보센터
학회 한국재료학회
학술대회 2015년 봄 (05/14 ~ 05/15, 구미코)
권호 21권 1호
발표분야 G. 나노/박막 재료
제목 Microwave-assisted low-temperature synthesis of CuBO2 and its electrical properties
초록 With the increasing demand for promising oxide materials in semiconductor industry delafossite materials have come up with satisfactory performance as conducting oxides. Copper boron oxide (CuBO2) is such a transparent conducting oxide with p-type nature, whose electrical properties is promising for high speed device applications. Here we report a novel way to synthesize CuBO2 nanostructure using microwave. Copper nitrate trihydrate (Cu(NO3)2.3H2O) and boric acid (H3BO3) were used as Cu and B precursors, respectively. The growth time and temperature were optimized at 2 h and 200 ºC, respectively. From scanning electron microscopy it was observed that the material has nanorod like shape with an average length of 500 nm. The UV-VIS spectral analysis revealed a sharp transition corresponding to around 4 eV. Hall measurements showed a high carrier concentration of 1018 cm-3 with p-type nature and reasonably good mobility of 2 cm2/ V-s with a resistivity of 0.36 Ω-cm.
저자 Pranab Biswas1, Sung Doo Baek2, Yun Cheol Kim1, Do Hoon Kim2, Do Kyun Kwon1, Jong Woo Kim2, Ji Hyeon Park1, Tae-Il Lee2, Jae-Min Myoung1
소속 1Department of Materials Science and Engineering, 2Yonsei Univ.
키워드 Delafossite; p-type; Microwave; Nanorod; Transparent conducting oxide
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