| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Energetic polyol using copper catalyst system via Click Chemistry |
| 초록 |
The triazolyl polyether diol derived from Poly(GAP-co-THF) and 1-Pentyne was synthesized by the 1,3 -dipolar cycloaddition with cupper sulfate pentahydrate (CuSO45H2O) and sodium ascrobate as a catalyst system and methylene chloride/water as a co-solvent system that called ‘Click Chemistry’. Synthesis of Poly(GAP-co-THF) used cationic ring-opening polymerization(CROP) and azidation. Structure and composition of synthesized triazolyl polyether diol was characterized by Fourier Transform Infrared Spectroscopy(FT-IR), Gel Permeation Chromatography(GPC) and Proton Nuclear Magnetic Resonance Spectroscopy(1H-NMR). |
| 저자 |
정권영1, 김태중1, 지상철1, 이범재1, 김진석2
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| 소속 |
1충남대, 2국방과학(연) |
| 키워드 |
Keyword : 1; 3-dipolar cycloaddition; click chemistry; triazolyl polyether diol; azidation;
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| E-Mail |
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