학회 |
한국화학공학회 |
학술대회 |
2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
권호 |
20권 2호, p.2474 |
발표분야 |
Ordered nanoporous materials symposium : State of the art 2014(촉매부문위원회 주제별 심포지엄) |
제목 |
Synthesis and Applications of Hierarchically Porous Metal-Organic Frameworks |
초록 |
Porous Metal Organic Frameworks (MOFs) are currently an important class of advanced functional materials due to their novel coordination structure, relatively facile preparation, special properties and potential practical applications. The zeotype cubic metal(III) carboxylates with giant cages labeled MIL-100 and MIL-101 (MIL: Materials of Institut Lavoisier) using iron and chromium and the cheap and simplest aromatic carboxylates such as terephthalate and trimesate, respectively. These solids possess several unprecedented features such as hierarchical pore structures including a zeotype architecture, mesoporous cages accessible through microporous windows, an exceptionally high cell volume and surface area, numerous unsaturated metal Lewis acid sites, and high hydrothermal and chemical stability. In this work, we will show that these materials present a combination of interesting properties that makes them very attractive candidates for several important applications such as catalysis and sorption. |
저자 |
Jong-San Chang1, Young Kyu Hwang2, U-Hwang Lee3
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소속 |
11Research Group for Nanocatalyst, 2Korea Research Institute of Chemical Technology (KRICT), 3Research Group for Nanocatalyst |
키워드 |
MOF; Synthesis; Catalyst; Adsorbent
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E-Mail |
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VOD |
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원문파일 |
초록 보기 |