학회 |
한국화학공학회 |
학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
권호 |
14권 1호, p.283 |
발표분야 |
미립자공학 |
제목 |
Dissolution Kinetics of Aluminum Can in Sec-butyl alcohol for Aluminum sec-butoxide |
초록 |
A kinetic study of dissolution reaction of Al can waste was conducted for the synthesis of Aluminum sec-butoxide (ASB). The reaction was examined at the condition of 3mol SBA/mol Al of stoichiometric ratio, adding 10^-3mol HgI2/mol Al for catalyst and no agitation at the reaction temperature ranging from 70 to 100℃. On the basis of the shrinking core model with the shape of flat plate, the first dissolution rate of Al can was controlled by chemical reaction. In the second stage, the dissolution rate is controlled by diffusion control through the ash layer. |
저자 |
유승준1, 이세일1, 곽동희1, 장희동2, 윤호성2, 황운연3
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소속 |
1서남대, 2한국지질자원(연), 3동양대 |
키워드 |
ASB; Used Al Can; Dissolution; Kinetics
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E-Mail |
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원문파일 |
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