화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 봄 (05/13 ~ 05/14, BEXCO(부산))
권호 14권 1호
발표분야 촉매
제목 Synthesis of polycarbonate from carbon dioxide and different type of epoxides using double metal cyanide catalysts
초록 In this work, the exploitation of double metal cyanide (DMC) catalyst, which is widely employed for epoxide polymerization to yield polyether polyols, have been used to prepare the copolymers of CO2 with cyclohexene oxide (CHO), vinyl cyclohexene oxide (VCHO) and cyclopentene oxide (CPO). A series of alkoxy alcohols used as complexing agent for DMC catalyst. The resulted copolymers obtained from the action of these catalysts are analysed by 1H NMR spectroscopy, infrared spectroscopy and gel permeation chromatography.
저자 하주영1, 김일1, 박은하2, 박성근2
소속 1부산대, 2코오롱플라스틱
키워드 Keyword : Carbon dioxide; Copolymerization; Double metal cyanide catalyst; Green process
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