화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구))
권호 13권 1호
발표분야 고분자
제목 Effect of Co-initiators on the Size Distribution of the Stable Poly (Styrene-co-Divinylbenzene) Microspheres in Acetone/Water Mixture
초록 The stable poly(styrene-co-divinylbenzene) [P(S-co-DVB)] spherical microspheres with narrow size distribution were prepared in acetone/water mixture in the presence of initiator, 2,2'-azobis(2,4-dimethyl valeronitrile) (V-65) and various co-initiators in the precipitation polymerization. The coinitiators used were potassium peroxodisulfate (KPS), ammonium peroxodisulfate (APS) and sodium peroxodisulfate (NaPS).The optimum ratios of acetone to water and the compositions of co-initiatorsfor the formation of narrow size distribution of P(S-co-DVB)were 49:11 (g/g), and 9:1 (g/g) for V-65 to KPS, 11:1 for V-65 to APS and 6:1 for V-65 to NaPS, respectively.
저자 최진영, 안명수, 최순자
소속 인하대
키워드 precipitation polymerization; co-initiator; co-solvent
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