| 학회 |
한국화학공학회 |
| 학술대회 |
2006년 가을 (10/27 ~ 10/28, 고려대학교) |
| 권호 |
12권 2호, p.2225 |
| 발표분야 |
에너지/환경 |
| 제목 |
Continuous MEO Process: The Study on Electrochemical Cell Characteristics and Model Fitting to Organic Oxidation |
| 초록 |
Electrochemical cells of various electrode materials and geometries were constructed and their performances for electrochemical regeneration of Ce(IV), which is essential for a continuous mediated-electrochemical-oxidation (MEO) process, were studied. Volt-amperic curves and cerium(III) electrolysis data conformed “limiting current” approach for anodic process. A new model is proposed to calculate a cerium consumption current in organic destruction MEO process and a number of “standard” cells for maintaining cerium(III)/cerium(IV) ratio at the same level. The model is based on a limiting current approach for cerium(III) oxidation at anode and previously derived by us continuous mode organic destruction model. Additionally cerium oxidation current was corrected by oxygen evolution. |
| 저자 |
Vasily V. Kokovkin, Subramanian Balaji, 정상준, Matheswaran Manickam, 문일식
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| 소속 |
순천대 |
| 키워드 |
Mediated electrochemical oxidation; Electrochemical cell; Cerium; Limiting current; Modeling fitting to organic oxidation |
| E-Mail |
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| 원문파일 |
초록 보기 |
