| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
Synthesis of Advanced Polymer Semiconductor with Silicon in DPP-Copolymer |
| 초록 |
We designed a new DPP-based donor−acceptor polymer semiconductor whose functionalized alkyl side chains can facilitate highly efficient mini-emulsion synthesis. DPP-TVT was selected as a reference polymer semiconductor, and its Si-analogue, SiDPP-TVT, in which the carbon atoms of the branched alkyl chains of DPP-TVT were replaced with silicon atoms, is newly synthesized. By substituting silicon at the branching position of the alkyl side chain, the volumetric portion of the alkyl side chain is expanded by increasing the C−Si−C bond angle and the Si−C bond length compared to the conventional C−C−C bond angle and C−C bond length. The extension of the alkyl side chain group could increase the solubility and hydrophobicity of the synthesized SiDPP-TVT, which enables better molecular affinity with ionic surfactant. |
| 저자 |
이경석1, 유성훈2, 송형근3, 조장환4, 권순기5, 정대성2, 김윤희3
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| 소속 |
1Department of Chemistry and RIGET, 2Gyeongsang National Univ., 3Department of Energy Science and Engineering, 4DGIST, 5Department of Materials Engineering and Convergence Technology and ERI |
| 키워드 |
OFET; diketopyrrolopyrrole; Water-Borne; mini-emulsion
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| E-Mail |
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