학회 |
한국고분자학회 |
학술대회 |
2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO)) |
권호 |
44권 1호 |
발표분야 |
분자전자 부문위원회 I |
제목 |
Enantioselective Graphene-Based Chemical Sensors Prepared via Chiral Functionalization |
초록 |
Discrimination of enantiomeric chemical molecules is one of the most important issues in chemical and biological fields due to the chirality-induced different properties of enantiomers. Here, we report the development of graphene transistor-type chemical sensors with pyrene-based chiral functionalization molecule. Chiral functionalization molecule itself showed different optical responsivity for addition of different β-citronellol enantiomers. Graphene transistor sensor was functionalized using simple solution deposition of chiral functionalization molecule via the strong π-π interaction between graphene and pyrene moiety of chiral functionalization molecule. Developed enantioselective chemical sensor successfully discriminated enantiomer of β-citronellol, in vapor phase sensing. Our results represent a significant step towards the improvement of chiral electronics field. |
저자 |
박철희1, Xiaobo Shang1, 정관영2, 곽상규2, 오준학1
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소속 |
1서울대, 2UNIST |
키워드 |
Graphene; Field-effect Transistor; Chirality; Chemical Sensor
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E-Mail |
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