| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
MFI-type zeolite coated ceramic tubular membrane divided tubular electrochemical cell for simultaneous generation of two electron mediators |
| 초록 |
The robustness and high volumetric conversion performance of tubular electrochemical reactor was disclosed to generate a single mediator. The present work explains two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated ceramic membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally. |
| 저자 |
A.G.Ramu, G.MUTHURAMAN, 김태형, 고병수, 문일식
|
| 소속 |
순천대 |
| 키워드 |
Zeolite tubular membrane; tubular electrochemical cell; two mediator generation; paired electrolysis
|
| E-Mail |
|
