| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 가을 (10/24 ~ 10/26, 대구 EXCO) |
| 권호 |
24권 2호, p.1668 |
| 발표분야 |
에너지 환경(Energy and Environment) |
| 제목 |
Evolution of tubular divided cell by MFI-type zeolite coated ceramic tubular membrane for concurrent generation of two electron mediators |
| 초록 |
Our recent work of tubular electrochemical reactor proved a single electron mediator can be generated. The present work explains two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated ceramic membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally. Key words: Zeolite tubular membrane, tubular electrochemical cell, two mediator generation, paired electrolysis |
| 저자 |
A.G.Ramu, G.Muthuraman, 문일식
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| 소속 |
순천대 |
| 키워드 |
에너지 환경 |
| E-Mail |
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| 원문파일 |
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