학회 |
한국공업화학회 |
학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
권호 |
26권 1호 |
발표분야 |
포스터-전기화학 |
제목 |
A novel electrochemical sensor based on bottlebrush-likeZnO nanowires decorated on carbon nanofibers for highly specific and sensitivedetection of silymarin in biologicalsamples |
초록 |
In this work, electro-etched carbon nanofibers(CNFs) were coated with bottlebrush-like zinc oxide (ZnO) nanowires via afacile hydrothermal method for the preparation of a CNF-ZnO nanocomposite as apromising electrode material for the trace level detection of silymarin. Thefabricated CNF-ZnO glassy carbon electrode (GCE) demonstrated a higher anodicpeak current, lower peak potential, and excellent sensing performance ofsilymarin compared to GCEs fabricated with ZnO or CNFs. The CNF-ZnO-GCEexhibited an appreciable linear response range (2–123 nM), good sensitivity(1.728 μA∙nM−1 cm2), and an ultra-low detection limit(1 nM). We also successfully showcased its specific sensing behavior for thesensing of silymarin in the presence of structurally similar compounds andmetal ions. Furthermore, the CNF-ZnO-GCE was effectively applied to realbiological and pharmacological samples for the efficient determination ofsilymarin, with which we obtained satisfactory recovery values. |
저자 |
김은수1, A.T. Ezhil Vilian2, 한영규2, 허윤석1
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소속 |
1인하대, 2동국대 |
키워드 |
Electrochemical sensor; Electrospun fibers; Carbon nanofibers; ZnO nanowires; Square-wave voltammetry; Silymarin |
E-Mail |
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