학회 | 한국공업화학회 |
학술대회 | 2005년 봄 (05/13 ~ 05/14, 충남대학교) |
권호 | 9권 1호 |
발표분야 | 촉매 |
제목 | Process for producing 5-ethylidene-2-norbornene (ENB) in the presence of a basic catalytic system |
초록 | 5-Ethylidene-2-norbornene (ENB), the third components of a terpolymer of ethylene, propylene and diene monomer (EPDM rubber), is commercially obtained by the isomerization of 5-vinyl-2-norbornene (VNB). A catalytic system consisting of an alkali metal hydride and an diamine was developed for the isomerization. Mechanistic study showed that the isomerization proceeds through a radical mechanism. |
저자 | 이소영1, 이제승1, 김훈식2, 이창하3 |
소속 | 1한국과학기술(연), 2경희대, 3연세대 |
키워드 | isomerization; basic catalyst |