화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 고분자가공/복합재료
제목 Thermal Responsive Graphene Nanosheets by Non-covalent Functionalization with LCST Tuned Block Copolymer
초록 Stimuli-responsive material undergoes interesting structural changes upon temperature, pH etc. Among them, temperature responsive material is convenient and less dependent on the chemical environment. Their applications have extended from drug release, smart windows, and other fields. Graphene based thermal-responsive material nanocomposite has prompted the development of thermal-responsive material because graphene has superior electrical, thermal and mechanical performance. In order to impart the stimuli-responsive ability to graphene, the common method is graphene functionalization by stimuli-responsive polymer. Non-covalent functionalization method is preferred for dispersing graphene simply. In this study, we synthesized poly((styrene)-block-(2-dimethyl(aminoethyl methacrylate (DMAEMA))) and prepared thermal responsive graphene by non-covalent functionalization. Furthermore, we tuned the low critical solution temperature using quaternization of DMAEMA moieties in block copolymer.
저자 권민호1, 한좋훈2, 이영실3, 백현종1
소속 1부산대, 2전남대, 3금오공과대
키워드 Thermal responsive polymer; graphene; LCST; block copolymer
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