| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
| 권호 |
22권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electron mediated degradation of cinnamyl chloride by electrochemically generated Co(I)(bipyridine) in aqueous CTAB solutions |
| 초록 |
An allyl chloride derivative, cinnamyl chloride, is one of the prominent environmental pollutant. This work reports cinnamyl chloride degradation by electrogenerated [Co(I)(bpy)3]+ (where bpy = 2,2’-bipyridine) electron mediator in environmentally benign CTAB aqueous solutions and examine the effects of phenyl substitution on the electrocatalytic degradation reaction. Cyclic voltammetry over a range of scan rates and cinnamyl chloride concentrations identified the rate limiting mechanism for Co(I)-catalyzed cinnamyl chloride degradation, which is compared with allyl chloride degradation for the aromatic group substitution effect |
| 저자 |
G.MUTHURAMAN, K. Chandrasekara Pillai, 문일식
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| 소속 |
순천대 |
| 키워드 |
Cinnamylchloride; aqueous micellar medium; [Co(I)(bpy)3]+; MER
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| E-Mail |
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