| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
정밀화학_포스터 |
| 제목 |
Synthesis of p-phenylenediamine (PPD) from p-Diiodobenezene using Copper(I) catalyst |
| 초록 |
Aramid fiber is well known to have excellent physical properties such as high thermal resistance and durability. In this work, for the production of p-Phenylenediamine(PPD), which is used as a precursor of para aramid fiber, the reaction of p-Diiodobenzene (PDIB) with a copper iodide catalyst was investigated. In general, as an amine donor for the copper-catalyzed amination of aryl halide, ammonia surrogates are used and results in additional process cost. However, in the present work, to avoid an unnecessary process and the production of undesirable compounds, ammonia was directly applied and found to work successfully. For the improvement of the reactivity, the reduction of the copper catalyst was achieved by using ascorbic acid and dihydroxyfumaric acid. |
| 저자 |
구기갑1, 박용기2, 최원춘2, 박선영2, 강나영2, 서휘민2, 김정석1, 이상용1
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| 소속 |
1서강대, 2한국화학(연) |
| 키워드 |
Catalyst; Amination; p-Phenylenediamine; arly halide; copper iodide
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| E-Mail |
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