| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
정밀화학_포스터 |
| 제목 |
Synthesis of Dieckol Mono-substituted Derivatives including Carbonyl group and Regioselectivity Characterization using by 2D-NMR technique |
| 초록 |
In this study, mono-substituted derivatives including carbonyl group were synthesized through the regioselective reaction of many phenolic OH groups of dieckol. O-acetylation reaction and O-benzoylation reaction were carried out to obtain the two derivatives. We have synthesized 9"-O-acetyl dieckol by reacting dieckol with acetyl chloride as a reactant, and found that the structure of the product and regioselective synthesis was achieved by 2D-NMR technique. We also have synthesized 9"-O-benzoyl dieckol by reacting dieckol with benzoyl chloride as a reactant, and found that the structure of the product and regioselective synthesis was characterized by the same technique. |
| 저자 |
김용균1, 강수민1, 황혜정2
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| 소속 |
1중앙대, 2한국뉴욕주립대 |
| 키워드 |
brown algae; O-acetylation; O-benzoylation; natural product; regioselectivity; 2D-NMR
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| E-Mail |
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