| 학회 | 한국공업화학회 |
| 학술대회 | 2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터) |
| 권호 | 16권 1호 |
| 발표분야 | 고분자 |
| 제목 | Synthesis Grafting Block Copolymer Using Anionic Ligated Polymerization |
| 초록 | This research is Synthesis of polyolefin and PMMA using controlling living ligated anionic polymerization, namely the goal is introduction of hard block graft polymer in soft polymer chain to raise Tg. In this polymerization system, initiating step was generated by using sec-BuLi and Al-ligand. Polymerization using bulky aluminum ligands such as MeAl(ODBP)2, it was an efficient initiating system having living manner. The grafting block-co-polymer were characterized by high temperature gel permeation chromatography and proton NMR. |
| 저자 | 조희원, 이범재, 배인주, 이혜림, 이형우 |
| 소속 | 충남대 |
| 키워드 | anionic ligated polymerization; polyolefin; PMMA; bulky aluminum phenoxide |
