| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 봄 (05/13 ~ 05/14, BEXCO(부산)) |
| 권호 |
14권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Ni(II) bis(benzimidazolyl) methylamine/pyridyl complexes for ethylene oligomerization reactions |
| 초록 |
The design and synthesis of efficient transition metal complex catalysts that precisely control olefin coordination polymerization and oligomerization attracted considerable interest recently. In that aspect, we have designed and synthesized a new series of Ni(II) complexes of bis(benzimidazolyl) methylamine/pyridyl ligands with varying electronic nature achieved by virtue of N-alkylation. The methyl amine derived complexes have a distorted octahedral geometry about the Ni center formed by three N atoms and three O atoms. The complexes showed productivity in excess of 1.6 x 106 g oligomer molNi-1 h-1 towards ethylene oligomerization producing butenes as the major product (~ 90%) along with the formation of hexenes(~10%). |
| 저자 |
비누, 김일, Yuri Shchipunov
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| 소속 |
부산대 |
| 키워드 |
Ethylene oligomerization; Single-site catalysts; and Bis(benzimidazolyl)Ni(II) complexes
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| E-Mail |
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