| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 |
15권 1호, p.1111 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Synthesis and Application of Sulfonic Acid Functionalized Mesoporous SBA-15 as an Efficient Support for Immobilization of Chiral Co(III) salens |
| 초록 |
The new application of sulfonic acid (-SO3H) functionalized SBA-15 was demonstrated as an effective method for the immobilization of chiral salen complexes on the surfaces. The cationic cobalt (III)salen complexes were immobilization by electrostatic interactions with alkyl and aromatic sulfonic groups via HO3S-functionalized linker on the inorganic support. The the cobalt(III)-SO3 salen complexes attached on the mesoporous supports via sulfonic acid linker have exhibited the excellent activity in the asymmetric ring opening reaction of racemic epoxide by water and phenol nucleophiles. |
| 저자 |
김용석, 곽소봉, 왕정함, 김건중
|
| 소속 |
인하대 |
| 키워드 |
Bimetallic salen; Immobilization; asymmetric reaction; SBA-15
|
| E-Mail |
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| 원문파일 |
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