| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_콜로이드·계면화학 |
| 제목 |
Metal-mediated Morphology Regulation of Self-Assembled Double-hydrophilic Block-Copolymers |
| 초록 |
We present a ‘crew-cut’ type micelle-like polymeric nanostructures prepared by the chelation of aquated cisplatin pharmacophore (PtII) to the block-copolymers of poly(ethylene glycol) and poly(acrylic acid). Depending on the PtII-feeding ratio and the length of PAA chains, the resulting morphology of self-assembled structures dramatically changed from spherical micelles to anisotropic perl-necklace and vesicle structures. 1H NMR and FT-IR analyses further exhibited hydrogen-bonding between PtII and the PEG residues plays an important role on the morphology variation. The characteristic colloidal structures related to such nanoparticles will be discussed. |
| 저자 |
최민호, 이상민
|
| 소속 |
가톨릭대 |
| 키워드 |
block-copolymer; nanoparticle; metal-mediated self-assembly
|
| E-Mail |
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