화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 기능성 고분자
제목 Low Temperature Fabrication of TiO2 Electrodes for Highly Efficient and Stable Flexible DSSCs
초록 Hierarchically structured TiO2 (HS-TiO2) was prepared on a flexible ITO-PEN substrate via electrospray deposition using a P25 powder in order to fabricate flexible DSSCs under low-temperature (150°C) conditions. The cell efficiency increased when using flexible ITO-PEN substrates post-treated by either a mechanical compression treatment or a chemical sintering treatment using titanium tetrabutoxide (TTB). An additional chemical sintering post-treatment involving TTB after compression treatment yielded faster electron diffusion, providing an efficiency of 5.57%. Finally, we revealed the binding mode of N719 on low-temperature processed HS-TiO2 surface and demonstrated strongly bound of N719 dyes on HS-TiO2 surfaces using stearic acid (SA) as coadsorbent. We found that the SA-treatment enabled the dye to anchor strongly on TiO2 surface and impeded desorption of anchored dye from TiO2 surface from the analysis of FT-IR and transient absorption spectroscopy.
저자 이호림1, 황대섭2, 조성무3, 서용석1, 김동영3
소속 1서울대, 2연세대, 3한국과학기술(연)
키워드 Flexible; Solar Cells; Low Temperature; Hierarchically Structure
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