| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis of well-defined poly(vinyl acetate)-b-poly(4-vinyl pyridine) block copolymers by a combination of CMRP and RAFT polymerization |
| 초록 |
Poly(vinyl acetate) (PVAc) macroinitiators were first synthesized via cobalt-mediated radical polymerization (CMRP) and then the cobalt complex attached to their chain end was converted into a dithioester group for the reversible addition-fragmentation chain transfer (RAFT) polymerization of 4-vinyl pyridine (4VP). The molecular weight distributions of the resulting PVAc-b-P4VP block copolymers were very narrow (Mw/Mn=1.11~1.17) even at high conversions. The PVAc-b-P4VP block copolymers were used as both a stabilizer and a photo-iniferter for the photo-induced dispersion polymerization of styrene (St). The PSt nanoparticles were characterized using 1H NMR, GPC, SEM, and FE-TEM. |
| 저자 |
전현정, 유영창, 이학준, 육지호
|
| 소속 |
인하대 |
| 키워드 |
block copolymer; dispersion polymerization; CMRP; RAFT polymerization; PSt particle
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| E-Mail |
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