화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-촉매
제목 Electrochemical Properties of Ordered Mesoporous Cobalt Oxides as a Negative Electrode for Li-ion Battery
초록 In recent days, as cutting-edge devices, such as cell phone, EV and ESS, become more sophisticated, the battery performance is required to be higher. As a result, metal oxides having a capacity several times larger than that of carbon have attracted attention as a candidate for a next-generation secondary battery. Cobalt oxide(CoO) is very attractive anode material due to its relatively high theoretical capacity of 716 mAh/g.
The nanostructured materials, especially mesoporous structure can play a leading role in electrochemical properties since its high surface area, large surface-to-volume ratio, and stable buffer effect against volume expansion. These characteristics provide especially anode materials with a lot of advantages which are fast ion/electron transfer, sufficient contact interface between active materials and electrolyte. Although bulk CoO maintains its own stable phase, mesoporous CoO gradually forms Co3O4 with Co metal through disproportionation process.
저자 이정호, 정지용, 권예림, 김지만
소속 성균관대
키워드 Disproportionation; Cobalt oxide; Li-ion battery
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