| 학회 | 한국고분자학회 |
| 학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 | 27권 2호, p.125 |
| 발표분야 | 고분자 가공/블렌드 |
| 제목 | Transesterification in Copolyetherester Blends |
| 초록 | Segmented block copolyetheresters have the hard segments that can cause transesterification. Ester interchange reactions are found in some polyester blends, which cause randomizing effect. The PBT/PBN copolymer can cocrystallize and show the isodimorphic crystallization against copolymer composition. Copolyetherester blend composed of cocrystallizable hard segments will show the melting endotherm. We blended the copolyetheresters having PBN or PBT hard segment together in solution and examined the influence of transesterification. Blending with the same hard segment content and time affected the sequence distribution and melting behavior. We compared the blend which showed ester interchange reaction with the random copolymer. |
| 저자 | 장영주, 김해영, 백두현 |
| 소속 | 충남대 |
| 키워드 | copolyetherester; blend; transesterification |
