화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 고분자_포스터
제목 Electro-Optical and Electrochemical Properties of Diglycidyl Fluorene Derivative
초록 With the rapid development of the electronic/electrical industry, epoxy resins are required not only to strengthen their inherent advantages such as good chemical resistance, low shrinkage, high-grade electrical insulation, excellent adherence to many substrates including metals, but also to overcome their disadvantages such as brittleness and flammability. Diglycidyl fluorene derivative was prepared via the reaction of 4,40-(9-fluorenylidene)diphenol and epibromohydrin by using aqueous NaOH solution. The film showed characteristic UV-visible absorption band at 313nm and PL maximum values of 369 and 426nm corresponding to the photon energy of 3.36 and 2.91 eV at 313nm excitation. This product exhibited deep-blue fluorescence on TLC plate. The cyclovoltamograms exhibited the irreversible electrochemical behaviors between the doping and undoping peaks.
저자 강석우1, 제갈영순2, 진성호3, 박영일4, 박종욱1
소속 1가톨릭대, 2경일대, 3부산대, 4한국화학(연)
키워드 fluorene derivative; glycidyl; synthesis; cyclovoltamogram; photoluminescence
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