| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Asymmetric catalysis in confined space provided by l-proline functionalized mesoporous silica with plugs in the pore |
| 초록 |
l-proline functionalized mesoporous silica was synthesized through direct synthesis method under acidic condition using Pluronic P123 as template and Sodium metasilicate nonahydrate as silica source. Microwave heating was applied, throughout hydrothermal aging treatment. The direct synthesis gave morphosynthesis of short channels and plugs in the pore structure. The unique characteristic of the pore provided chiral enhancement in the diethyl malonate addition and Aldol condensation reaction. Moreover, the properties of plugged proline mesoporous silica has been studied for chiral adsorbtion of D/L alanine and observed by cyclo dichroism (CD) technique. |
| 저자 |
에코아디, 박상언, 정승민
|
| 소속 |
인하대 |
| 키워드 |
proline; plug; asymmetric catalysis
|
| E-Mail |
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