| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
환경.에너지_포스터 |
| 제목 |
Effect of polymer modified electrodes towards generation of low valent ligand free electron mediator Co(I) by paired electrolysis for air pollutant removal |
| 초록 |
Ligand free reductive election mediators was able to stabilize in solution by adjusting the electrolyte concentration but, deposited as metal on the electrode surface restrict its application in air pollutant removal process. Through the present investigation, some polymeric modified electrodes were attempted towards generation of Co(I). Here, polyaniline, PEDOT (polyethylenedioxythiophene), and polypyrrole electrodes were electrochemically prepared and used as cathode in a divided electrolytic cell to generate Co(I). Each polymerized electrodes were confirmed by the cyclic voltammetry and SEM–EDS analyses. Efficiency of the prepared polymeric electrodes were tested on Co(II)(OH)4 reduction in 10 M KOH solution at cathodic half-cell. Finally, a comparative analysis was made to identify the suitable electrode. |
| 저자 |
G. MUTHURAMAN, PERUMAL SILAMBARASAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
Polymeric electrodes; Reductive electron mediator; Electro polymerization; Ligand free mediator.
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| E-Mail |
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