| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Selective electrochemical generation of Cu(I) in bimetallic compound of Cu(II)[Ni(CN)4]2- in alkaline medium using divided cathodic electrolytic cell |
| 초록 |
In mediated electrocatalytic reduction (MER) process, quantification of mediatoer ion is key role for further processes. In bimetallic complex, the identification is very difficult due to two metal ions reduced simultaneuoly. The present investigation focuses on Cu(I) identification in bimetallic Cu(II)[Ni(II)(CN)4]2- during electrolytic reduction process. At first, reduction efficiency of individual compounds identified at given current density in 10 M KOH medium. Then, ORP values with electrolysis time found to differentiate the metal ions reduction. UV-visible, and CV analyses were shown to identify the exact metal ion reduction, especially Cu(I) formation. The present analysis will help to use Cu(I) as electrocatalyst in a bimetallic complex. |
| 저자 |
G. MUTHURAMAN, A.G.Ramu, 문일식
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| 소속 |
순천대 |
| 키워드 |
Homogeneous mediator; Cu(I); bimetallic complex; MER..
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| E-Mail |
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