| 학회 | 한국화학공학회 |
| 학술대회 | 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
| 권호 | 25권 2호, p.1667 |
| 발표분야 | 에너지 환경 (Energy and Environment) |
| 제목 | Effect of two electron mediator generation using one side coated MFI-type zeolite on ceramic tube |
| 초록 | Elimination of ion cross over in membrane is a key parameter in many field. The present investigation attempts to check one side MFI-type zeolite coating on a ceramic tube by two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- crossover. Through the on side coated MFI-type zeolite tubular membrane, electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved by paired electrolysis and confirmed by ORP change. No metal ion crossover via one side coated MFI-zeolite ceramic membrane confirmed by UV-visible spectral analysis. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the one side coated MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. The uncoated side ceramic tube was dissolved slowly. Key words: one side MFI-zeolite coating, tubular membrane, tubular electrochemical cell, no-crossover |
| 저자 | 이보열, G.Muthuraman, A.G.Ramu, 문일식 |
| 소속 | 순천대 |
| 키워드 | 에너지 환경 |
| 원문파일 | 초록 보기 |
