| 학회 | 한국공업화학회 |
| 학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 22권 2호 |
| 발표분야 | 고분자_포스터 |
| 제목 | Synthesis of acrylic resins having acetal group capable of acid degradation |
| 초록 | Due to recent environmental regulations and interest in developing environment friendly materials, much attention has been paid to the recovery or decomposition of polymeric materials. It is difficult or impossible to completely remove the UV-cured resin from the surface of the substrate because it is not dissolved after curing. In this study, acrylate containing acetal group which can be decomposed by acid treatment was synthesized by reaction of divinyl ether with acrylic acid. The degree of substitution of acrylate was confirmed by 1H-NMR analysis, and curing behavior was observed by irradiating 370 nm ultraviolet light using PI-TPO, DMPA, and Darocur 1173 as photoinitiators. Degradation behavior was evaluated by introducing various acidic conditions into the cured resin. As a result, it was confirmed that the acetal group was decomposed under proper acidic conditions. |
| 저자 | 장상은, 류상욱 |
| 소속 | 충북대 |
| 키워드 | UV curing; Acrylate resin; Acid-catalyzed degradation |
