| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터) |
| 권호 |
14권 2호 |
| 발표분야 |
환경.에너지 |
| 제목 |
Excess properties at 298.15 K for binary and ternary mixtures of ether compounds and methanol with trihexyltetra decylphosphonium chloride |
| 초록 |
Ionic liquids (ILs) have recently been categorized as green solvents in industrial separation methods because of their extremely low vapor pressure and thermal stability. In this work, we report the excess molar volume(VE) and deviations in molar refraction(ΔR) data at 298.15 K under atmospheric pressure for the following binary systems: {methyl tert-butyl ether (MTBE)+methanol},{Tert-amyl methyl ether (TAME)+ methanol} with trihexyltetra decylphosphonium chloride. The experimental binary VE and ΔR were correlated with the Redlich-Kister polynomial. And the ternary systems from the binary contribution model of Radojkovi with correlated sub-binary Redlich-Kister parameters. |
| 저자 |
이재연1, 박소진1, 한규진2
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| 소속 |
1충남대, 2대덕대 |
| 키워드 |
excess properties; density; refractive index; ionic liquids
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| E-Mail |
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