| 학회 |
한국고분자학회 |
| 학술대회 |
2006년 봄 (04/06 ~ 04/07, 일산킨텍스) |
| 권호 |
31권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Construction of ortho-Phenylene-Bridged Cp/Amido Titanium Complexes by Suzuki-Coupling Reaction and Their Ethylene/1-Hexene Copolymerization |
| 초록 |
A new synthetic route was devised by using the Suzuki-coupling to prepare ortho-phenylene-bridged Cp/amido titanium complexes. The key starting material in this route, boronic acid 1 can be prepared in 30g-scale. The boronic acid is excellent substrates for the Suzuki-coupling reaction and the cyclopentenone compounds 2 are afforded in excellent yields. The cyclopentenone compounds can be easily transformed to the cyclopentadiene compounds 3 from which various ortho-phenylene-bridged Cp/amido titanium complexes are prepared. Several complexes were characterized by X-ray crystallography and some of them show higher activity, higher incorporation of 1-hexetene, and higher molecular weights than the standard CGC [(5-Me4Cp)CH2CH2(NtBu)]TiCl2. |
| 저자 |
이분열, 조대준, 오춘희
|
| 소속 |
아주대 |
| 키워드 |
Metallocene; Polymerization; Polyethylene
|
| E-Mail |
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