학회 |
한국화학공학회 |
학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
권호 |
21권 1호, p.696 |
발표분야 |
열역학 |
제목 |
Study on Gas Hydrate Inhibition based on Ionic Liquids |
초록 |
Ionic liquids are combined with a polymer kinetic hydrate inhibitor for methane hydrate inhibition. The inhibition effects of the mixtures consisting of poly(N-vinylcaprolactam) (PVCap) and ionic liquids such as N-ethyl-N-methylimidazolium tetrafluoroborate([EMIM][BF4]), N-butyl-Nmethylpyrrolidinium tetrafluoroborate([HEMP][BF4]) were investigated.[1] The induction times for [EMIM][BF4] + PVCap, [BMP][BF4] + PVCap, and [HEMP][BF4] + PVCap at 0.5wt% of IL and 0.5wt% of polymer were 120.3, 65.8 and 184.9 min, respectively.[2] In particular, the inhibitor including [HEMP][BF4] enormously renew induction time and decreased hydrate growth rate by forming hydrogen bonding between ionic liquid and water molecules.[3] It was found that all ionic liquids synthesized in this study are powerful synergists for the standard polymer inhibitor. |
저자 |
강승태1, 차종호2, 강성필3, 김기섭4
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소속 |
1한국교통대, 2National Energy Technology Laboratory, 3USA, 4한국에너지기술(연) |
키워드 |
Ionic liquids; Gas hydrate; Inhibitor; Induction time
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