초록 |
Amphiphilic, gradient copolymers have interesting aqueous solution properties that may lead to many potential applications such as nanoreactors, gene delivery and drug delivery systems. In this work, we report on the preparation of amphiphilic gradient copolymers, poly[poly(ethylene glycol) methyl ether methacrylate-co-styrene](poly(PEGMA–co-Styrene)), via ATRP. We determined the reactivity ratio of PEGMA and Styrene in ATRP. Also, the micellization behavior of the poly(PEGMA–co-Styrene) copolymers in aqueous solutions was studied. |