초록 |
Helical nanostructure of the conjugated polymer has generated great interest in optoelectronic devices such as optical information processing, security‐enhanced optical communication, etc. due to its circularly polarized light detection ability. As the requirements for miniaturized, wearable, and stretchable electronic devices with advanced memory capabilities have increased recently, interest in ferroelectric polymer has increased significantly. A molecular engineering for helicity control is highly desired in a controlled manner of dimension and size. Herein, we report the helical assembly of ferroelectric polymers based on a conducting nanowire template that prevents neutralization of ferroelectric polarization. Solution-state helical assembly promoted by additives involves the sergeant-soldier effect of ferroelectric polymers. Amplified chirality of resultant hybrid was clearly observed in a circular dichroism spectroscopy. |