초록 |
Metal–organic frameworks (MOFs), a class of crystalline material comprising metal or metal-cluster nodes connected by organic linkers, are promising as battery or superacapcitor electrodes. MOFs provide a highly capacitance and tunable platform for integrating desirable properties, including high surface area, porosity, recyclability, and crytallinity. According to recent research, heterobimetallic Co–Al active sites were selectively installed in a single step on NU-1000, by simply mixing the MOF with the organometallic precursor. Heterometallic active sites are of great value in exploiting the harnessing multimetallic cooperativity because they provide a greater chemical space that occurs in every possible metal-to-metal combination. We designed heterobimetallic complex containing strong metal-metal interactions within a MOF for supercapacitor electrode. Electrochemical properties were characterized by cyclic voltammetry (CV) and charge-discharge (CD) in 6M KOH electrolyte. |