| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Kinetic Resolution of Terminal Epoxides with Phenols Promoted by Heterometallic Co-Al and Co-Ga Salen Complexes |
| 초록 |
The binuclear chiral (salen ) Co complexes bearing Lewis acid salt (Al and Ga ) and 4-nirobenzene sulfonic acid (NBS) catalyze the enantioselective ring opening of terminal epoxides with phenol derivatives. The easily prepared complexes exhibited very high catalytic reactivity and enantioselectivity for the asymmetric ring opening of terminal epoxides with phenol and consequently provide enantiomerically enriched corresponding α-aryloxy alcohols (up to ＞99% ee). |
| 저자 |
라울, 안철흥, 김건중
|
| 소속 |
인하대 |
| 키워드 |
heterometallic chiral complex; kinetic resolution; α-aryloxy alcohols; terminal epoxides.
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| E-Mail |
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